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1、 The Lubrizol Corporation 2006, all rights reserv ed Metalworking Additives 金屬加工添加劑 The Lubrizol Corporation 2007, all rights reserv ed Agenda 議程 Introduction 概況介紹 Metalworking Capabilities and Support 金屬加工系列產(chǎn)品線(xiàn)和技術(shù)支持 Product Offering and Formulation Advices 產(chǎn)品介紹和配方舉例 Questions 問(wèn)題

2、 The Lubrizol Corporation 2007, all rights reserv ed Sulfurized EP Additives, Traditional Soluble Oil Emulsifier 硫系極壓劑及乳化劑產(chǎn)品 Waterbased Additives, Emulsifier Expertise, Speciality Polymeric Esters 水基添加劑、乳化劑和聚合酯 Water based Additives, Corrosion Inhibitor Expertise,水基防銹及防腐 蝕劑 Biocides殺菌劑 Rust Preve

3、ntives, Water based Corrosion Inhibitors 防銹劑 Rust Preventives, Natural Sulfonate supply, Thixotropic Gelled Sulfonate 防銹劑、磺酸鹽 The Lubrizol Corporation 2007, all rights reserv ed Global Support 全球技術(shù)支持 Technical laboratories 技術(shù)實(shí)驗(yàn)室 Wickliffe, OH USA Brecksville, OH USA Hazelwood, England Spar

4、tanburg, SC USA Metalworking Research low aluminum staining tendency 能夠增強(qiáng)配方的 潤(rùn)滑性 ，對(duì)鋁基本無(wú)腐蝕。 The Lubrizol Corporation 2007, all rights reserv ed LUBRIZOL 5636: Benefits Summary特點(diǎn)總結(jié) Ability to produce low foam emulsion products that solve problems at end user operations LZ5636可配制低泡沫乳液，從而解決終端用

5、戶(hù)使用過(guò)程中出現(xiàn)的諸多問(wèn)題。 Reduce reliance on defoamer treatments that provide temporary solutions 減少了對(duì)消泡劑的依賴(lài)性，消泡劑所能提供的只是短期和暫時(shí)的效果。 Product performance differentiation vs competitors using traditional emulsion approaches 相比傳統(tǒng)乳化技術(shù)，它可使產(chǎn)品性能差異化，滿(mǎn)足各種不同需求 New chemistry for the industryalternative to sulfona

6、tes that offer less performance and uncertain supply future LZ5636是行業(yè)中 新穎的化學(xué)品 ， 可做為 磺酸鈉的替代品 使用?；撬徕c與之 相比性能較差，并且在將來(lái)供應(yīng)很可能極不穩(wěn)定。 Economically viable approach for a wide range of finished fluid emulsion types & product performance levels 對(duì)廣泛的乳化液類(lèi)型和不同性能和檔次 的產(chǎn)品，它都是一個(gè)經(jīng)濟(jì)可行的解決方案。 The Lubrizol Corporatio

7、n 2007, all rights reserv ed Lubrizol 5477 SOE Package for Paraffinic Oil Lubrizol 5477-用于石蠟基油的全新可溶油復(fù)合劑 Used in variety of paraffinic base stock with 3% Contram ST-1 可以和 3%Contram ST-1并用于廣泛的石蠟基油 Contains copper corrosion inhibitor 含有銅合金緩蝕劑 Provides good hard water stability, high pH value

8、, Cu protection, good bloom and rust protection 優(yōu)異的硬水穩(wěn)定性，較高的 pH值，銅合金保護(hù)，自乳化性能和防銹保護(hù) Used to make conventional and EP type soluble oils 可以調(diào)配通用和極壓型乳化液 Adjustments with fatty acid, triethanolamine or other coupling agents may be required to obtain emulsion stability desired 可以使用脂肪酸、 TEA或其他偶合劑來(lái)調(diào)整

9、乳液安定性 The Lubrizol Corporation 2007, all rights reserv ed SOLUBLE BASE 133U112C in ESSO150SN Base 133U112C wt% 15.0 ESSO 150SN wt% 82.0 Contram ST-1 wt% 3.0 1.Concentrate stability IP311 a) High Temp 50 /14days OK b) Low Temp 0 /14days OK 2.pH value 5% in DI H2O 9.74 5% in Shanghai tap water (180p

10、pm) 9.46 3. Emulsion stability IP263 5% in 200ppm 50 Cream/Oil 0.3/0.0 5% in 400ppm 50 Cream/Oil 0.3/0.1 4. Rust Protection IP287, 5% 100ppm rust area <1% 200ppm rust area 1% 5. Cu Corrosion 5% in tap water, ASTM D130 100 /3hrs Class 1b 5.Foam Test IP312, 5% in 180ppm start 120ml 1min 0 (3sec) 6

11、. Bloom 自乳化性能 Inversion 1 Formulate at 15% in ESSO150SN ( or GaoQiao, DaLian) Addition of Contram ST-1 Excellent hard water stability The Lubrizol Corporation 2007, all rights reserv ed SOLUBLE BASE 133U112C in ESSO150SN Base 133U112C wt% 15.0 ESSO 150SN wt% 82.0 Contram ST-1 wt% 3.0 1.Concentra

12、te stability IP311 a) High Temp 50 /14days OK b) Low Temp 0 /14days OK 2.pH value 5% in DI H2O 9.74 5% in Shanghai tap water (180ppm) 9.46 3. Emulsion stability IP263 5% in 200ppm 50 Cream/Oil 0.3/0.0 5% in 400ppm 50 Cream/Oil 0.3/0.1 4. Rust Protection IP287, 5% 100ppm rust area 316 316 316 D17

13、43 (Rust, distilled water) pass pass fail, tr D1264 (Wash out, %) 3.3% 1.6 1.3 D4049 (Spray off, %) 24.4% 8.1 14.2 Grease Performance of Lubrizol 86GR Based Grease LZ86GR磺酸鈣潤(rùn)滑脂性能 The Lubrizol Corporation 2006, all rights reserv ed 提高潤(rùn)滑脂高溫流變性的添加劑 Lubrizol 5370C The Lubrizol Corporation 2007, all

14、rights reserv ed 提高潤(rùn)滑脂滴點(diǎn) LZ 5370C 硼酸脂類(lèi)型， 2.7% wt 的硼 提高鋰基脂（ 12HSA）的滴點(diǎn) 幫助復(fù)合鋰基脂穩(wěn)定滴點(diǎn) 幫助提高極壓和抗磨性 加劑量 1 - 3% 與 LZ 1395復(fù)配可獲得更高的滴點(diǎn) 與其他競(jìng)爭(zhēng)產(chǎn)品相比， 不通過(guò)欺瞞 D2265滴點(diǎn)檢測(cè)儀來(lái)獲得需要 的滴點(diǎn)。實(shí)際上是改善潤(rùn)滑脂的高溫流變性能來(lái)提高滴點(diǎn)。 The Lubrizol Corporation 2007, all rights reserv ed Testing AS M D 2265: 滴點(diǎn)測(cè)試儀 GR6 40/GR-SP 37 1-2

15、7-98 Thermometer Test Tube Test Cup Test Grease Applied to the Wall of Cup Thermometer Does Not Touch Grease Aluminum Block Oven The Lubrizol Corporation 2007, all rights reserv ed Testing ASTM D 2265: 潤(rùn)滑脂滴點(diǎn)測(cè)試 Heating Unit with Observation Ports “儀器欺瞞 ”是指將油完全從潤(rùn)滑脂中分離出去，形成 一個(gè)長(zhǎng)的油滴，懸掛在油杯上而不滴落 -這樣形成一

16、個(gè) 潤(rùn)滑脂具有很好高溫滴點(diǎn)的假象。 The Lubrizol Corporation 2007, all rights reserv ed Lithium 12-Hydroxystearate Greases ASTM D2265 Dropping Point Test Results MoDTP = Molybdenum di(2-ethylhexyl) phosphorodithioate, an additive typically recommended at 0.75%/wt to improve the dropping point of grease. 1 2 3 4 5

17、 6 Base Grease 100 98.5 97 97 94.5 99.25 LZ 5370C 1.5 3.0 1.5 1.5 LZ 1395 1.5 LZ 5235 4.0 MoDTP 0.75 Drop Point ( C) 207 263 283 316 316 205 In simple lithium greases, MoDTP has NO effect The Lubrizol Corporation 2007, all rights reserv ed Lithium Complex Greases (Azelaic Acid/12-HSA) ASTM D2265 D

18、ropping Point Test Results 1 2 3 4 5 6 Base Grease 100 98.5 97 97 94.5 99.25 LZ 5370C 1.5 3.0 1.5 1.5 LZ 1395 1.5 LZ 5235 4.0 MoDTP 0.75 Drop Point ( C) 316 315 313 315 316 305 MoDTP = Molybdenum di(2-ethylhexyl) phosphorodithioate, an additive typically recommended at 0.75%/wt to improve the dr

19、opping point of grease. In a good Li complex, MoDTP has reduced the drop pt. The Lubrizol Corporation 2007, all rights reserv ed Failed Lithium Complex Greases (Azelaic Acid/12-HSA) ASTM D2265 Dropping Point Test Results 1 2 3 4 5 6 Base Grease 100 98.5 97 97 94.5 99.25 LZ 5370C 1.5 3.0 1.5 1.5

20、 LZ 1395 1.5 LZ 5235 4.0 MoDTP 0.75 Drop Point ( C) 223 282 298 316 316 283 MoDTP = Molybdenum di(2-ethylhexyl) phosphorodithioate, an additive typically recommended at 0.75%/wt to improve the dropping point of grease. The Lubrizol Corporation 2007, all rights reserv ed LZ 5370C 總結(jié) 提高鋰基脂（ 12HSA）的熱抵抗能力 滴點(diǎn)提高與加入量成比例 . 不影響其他功能劑的性能 . 可以幫助低滴點(diǎn)復(fù)合鋰基脂，以獲得正常的熱抵抗能力 . 與鋅鹽（ LZ1395/LZ5235）配合可獲得更好的性能 . The Lubrizol Corporation 2007, all rights reserv ed Thank You